Quick Recap — Hess's Law & Thermochemistry

  • Hess's law: the total enthalpy change is the same by any route (because HH is a state function); thermochemical equations can be added.
  • ΔH=ΔU+ΔngRT\Delta H=\Delta U+\Delta n_g RT (Δng=\Delta n_g= moles of gaseous products −- reactants).
  • For ideal gas: Cp−Cv=RC_p-C_v=R.
  • Enthalpy of reaction =∑ΔHf∘(products)−∑ΔHf∘(reactants)=\sum\Delta H_f^\circ(\text{products})-\sum\Delta H_f^\circ(\text{reactants}). Neutralisation of a strong acid by a strong base ≈−57.1\approx-57.1 kJ/mol.