Quick Recap — Matter Waves (de Broglie)

  • de Broglie wavelength: λ=hp=hmv=h2mKE=h2mqV\lambda=\dfrac{h}{p}=\dfrac{h}{mv}=\dfrac{h}{\sqrt{2m\,KE}}=\dfrac{h}{\sqrt{2mqV}}.
  • Electron shortcut: λ=12.27V\lambda=\dfrac{12.27}{\sqrt{V}} Å (with VV in volts).
  • Trends: λ1p\lambda\propto\dfrac{1}{p}, so heavier or faster particles have shorter wavelengths; macroscopic objects have immeasurably tiny λ\lambda.
  • Confirmation: the Davisson–Germer experiment (electron diffraction) verified the wave nature of matter. In a Bohr orbit, 2πrn=nλ2\pi r_n=n\lambda.

Worked mini-example. An electron accelerated through 100 V has λ=12.27100=1.23\lambda=\dfrac{12.27}{\sqrt{100}}=1.23 Å — comparable to atomic spacings, hence electron diffraction.