Quick Recap — Shielding, Contraction & Reasoning

  • Effective nuclear charge ZeffZ_{eff} rises across a period (poor shielding by same-shell electrons); shielding order s>p>d>fs>p>d>f.
  • Lanthanoid contraction makes the second- and third-row transition metals similar in size (e.g. Zr \approx Hf).
  • Anomalous 2nd-period behaviour: small size, no d-orbitals, high electronegativity.
  • Successive ionisation enthalpies jump sharply when a noble-gas core is broken into.