Quick Recap — Oxidation State, Isomerism Types & Reactions

  • Isomerism: structural (ionization, hydrate, linkage, coordination) and stereo (geometrical cis-trans, optical).
  • Ionization isomers give different ions in solution (e.g. [Co(NH3)5Br]SO4[Co(NH_3)_5Br]SO_4 vs [Co(NH3)5SO4]Br[Co(NH_3)_5SO_4]Br).
  • EAN =Z(oxidation state)+2(CN)=Z-(\text{oxidation state})+2(\text{CN}).
  • Precipitation test: only ions outside the coordination sphere are free (e.g. free ClCl^- precipitates as AgCl).