Quick Recap — Naming, Reagents & Bond Fission

  • IUPAC: pick the longest chain (root), give substituents the lowest locants.
  • Electrophile = electron-deficient (H+H^+, NO2+NO_2^+, carbocations, BF3BF_3, AlCl3AlCl_3); nucleophile = electron-rich (OHOH^-, CNCN^-, NH3NH_3, halide ions).
  • Inductive effect acts through sigma bonds: alkyl is +I+I (donating); NO2-NO_2, CN-CN, halogens are I-I (withdrawing).
  • Homolysis \to free radicals; heterolysis \to a carbocation and an anion.