Hard Practice — Combined Identification & Titration

Chain the evidence: use two or more tests together (flame colour + precipitate, or functional-group tests) to identify a salt or compound, and carry titration stoichiometry (N1V1=N2V2N_1V_1=N_2V_2 or mole ratios) through to purity/percentage.

  • KMnO4KMnO_4 (n = 5, acidic), oxalic acid (n = 2), K2Cr2O7K_2Cr_2O_7 (n = 6); %\% purity from the titre.
  • Tests: aldehyde (Tollens'/Fehling'), CH3COCH_3CO- (iodoform), acid (NaHCO3NaHCO_3), phenol (FeCl3FeCl_3).