Quick Recap — Multi-step Electrochemistry (Hard)

  • Ecell∘=Ecathode∘−Eanode∘E^\circ_{cell}=E^\circ_{cathode}-E^\circ_{anode}; Nernst: E=E∘−0.059nlog⁡QE=E^\circ-\dfrac{0.059}{n}\log Q; ΔG∘=−nFE∘\Delta G^\circ=-nFE^\circ; log⁡K=nE∘0.059\log K=\dfrac{nE^\circ}{0.059}.
  • Faraday: m=MnFItm=\dfrac{M}{nF}It, Q=ItQ=It; Λm=κ×1000C\Lambda_m=\dfrac{\kappa\times1000}{C}, α=ΛmΛm∘\alpha=\dfrac{\Lambda_m}{\Lambda^\circ_m}.
  • Watch the number of electrons (nn) per ion and per gas molecule.