Quick Recap — Multi-step Electrochemistry (Hard)

  • Ecell=EcathodeEanodeE^\circ_{cell}=E^\circ_{cathode}-E^\circ_{anode}; Nernst: E=E0.059nlogQE=E^\circ-\dfrac{0.059}{n}\log Q; ΔG=nFE\Delta G^\circ=-nFE^\circ; logK=nE0.059\log K=\dfrac{nE^\circ}{0.059}.
  • Faraday: m=MnFItm=\dfrac{M}{nF}It, Q=ItQ=It; Λm=κ×1000C\Lambda_m=\dfrac{\kappa\times1000}{C}, α=ΛmΛm\alpha=\dfrac{\Lambda_m}{\Lambda^\circ_m}.
  • Watch the number of electrons (nn) per ion and per gas molecule.