Quick Recap — Conductance, Batteries & Corrosion

  • Strong electrolyte: Λm\Lambda_m rises slightly on dilution; weak electrolyte: rises steeply. Degree of dissociation α=ΛmΛm\alpha=\dfrac{\Lambda_m}{\Lambda^\circ_m}.
  • Ecell>0K>1E^\circ_{cell}>0\Rightarrow K>1; the Nernst factor 0.059 applies at 298 K.
  • Electrolysis: molten NaClNaCl\to Na + Cl2Cl_2; aqueous NaClH2NaCl\to H_2 (cathode) + Cl2Cl_2 (anode).
  • Corrosion protection: galvanising, and sacrificial anodes (a more reactive metal like Zn/Mg).