What Makes Charge Flow? Potential Difference

Charges do not flow in a copper wire by themselves - just as water in a perfectly horizontal tube does not flow until there is a pressure difference. For charges to flow in a conductor, there must be a difference of electric pressure, called the potential difference, across it.

This potential difference is produced by a cell or a battery (one or more cells). The chemical action inside a cell maintains the potential difference across its terminals, even when no current flows. When connected in a circuit, this potential difference sets the charges in motion and drives the current. To keep the current flowing, the cell continually spends its stored chemical energy.

Voltmeter in parallel measuring potential difference

Defining Potential Difference: V = W/Q

The electric potential difference between two points is the work done to move a unit charge from one point to the other:

V=WQV = \frac{W}{Q}

The SI unit of potential difference is the volt (V), named after Alessandro Volta.

One volt is the potential difference between two points when 1 joule of work is done to move a charge of 1 coulomb from one point to the other:

1 V=1 joule1 coulomb=1 J C11\ \text{V} = \frac{1\ \text{joule}}{1\ \text{coulomb}} = 1\ \text{J C}^{-1}

Potential difference is measured by a voltmeter, which is always connected in parallel across the two points between which the potential difference is to be measured.

Key Point: Ammeter → series; Voltmeter → parallel.

Solved Examples

Example 1: Work done to move a charge (NCERT 11.2)

How much work is done in moving a charge of 2 C across two points having a potential difference of 12 V?

Solution: W=VQ=12 V×2 C=24 JW = V Q = 12\ \text{V} \times 2\ \text{C} = 24\ \text{J}

Example 2: Energy given by a battery

How much energy is given to each coulomb of charge passing through a 6 V battery?

Solution: V=W/QV = W/Q, so for Q=1Q = 1 C, W=VQ=6 V×1 C=6 JW = VQ = 6\ \text{V} \times 1\ \text{C} = 6\ \text{J}. Each coulomb gains 6 J of energy.

Example 3: Potential difference from work and charge

If 45 J of work is done to move 5 C of charge between two points, find the potential difference.

Solution: V=WQ=45 J5 C=9 VV = \frac{W}{Q} = \frac{45\ \text{J}}{5\ \text{C}} = 9\ \text{V}